{"id":6036,"date":"2024-07-16T16:30:20","date_gmt":"2024-07-16T08:30:20","guid":{"rendered":"https:\/\/www.51dea.com\/archives\/6036"},"modified":"2024-07-16T16:30:20","modified_gmt":"2024-07-16T08:30:20","slug":"%e4%b8%81%e5%9f%ba%e7%a1%ab%e9%86%87%e9%94%a1%e5%90%88%e6%88%90%e6%96%b9%e6%b3%95%e4%b8%8e%e5%b7%a5%e8%89%ba","status":"publish","type":"post","link":"https:\/\/www.51dea.com\/archives\/6036","title":{"rendered":"\u4e01\u57fa\u786b\u9187\u9521\u5408\u6210\u65b9\u6cd5\u4e0e\u5de5\u827a"},"content":{"rendered":"

\u4e01\u57fa\u786b\u9187\u9521\u7684\u5408\u6210\u65b9\u6cd5\u4e0e\u5de5\u827a<\/h3>\n

\u4e01\u57fa\u786b\u9187\u9521\uff08Butylmercaptostannane\uff09\uff0c\u5316\u5b66\u5f0fC4H10OSSn\uff0c\u662f\u4e00\u79cd\u5e38\u7528\u7684\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u4e3b\u8981\u7528\u4e8e\u805a\u6c2f\u4e59\u70ef\uff08PVC\uff09\u7684\u7a33\u5b9a\u5242\uff0c\u56e0\u5176\u4f18\u79c0\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u900f\u660e\u6027\u800c\u53d7\u5230\u9752\u7750\u3002\u4e0b\u9762\u5c06\u63a2\u8ba8\u51e0\u79cd\u4e01\u57fa\u786b\u9187\u9521\u7684\u5178\u578b\u5408\u6210\u65b9\u6cd5\u53ca\u5176\u5de5\u827a\u6d41\u7a0b\u3002<\/p>\n

\u5408\u6210\u8def\u7ebf\u4e4b\u4e00\uff1a\u4e01\u57fa\u6c2f\u5316\u9521\u4e0e\u786b\u9187\u7684\u53cd\u5e94<\/h4>\n

\u8fd9\u662f\u5408\u6210\u4e01\u57fa\u786b\u9187\u9521\u5e38\u89c1\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u4e01\u57fa\u6c2f\u5316\u9521\uff08BuSnCl3\uff09\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\uff0c\u4e0e\u4e01\u57fa\u786b\u9187\uff08BuSH\uff09\u5728\u9002\u5f53\u7684\u6eb6\u5242\u548c\u6e29\u5ea6\u4e0b\u8fdb\u884c\u53cd\u5e94\uff0c\u751f\u6210\u4e01\u57fa\u786b\u9187\u9521\u3002\u8be5\u53cd\u5e94\u53ef\u4ee5\u8868\u793a\u4e3a\uff1a<\/p>\n

BuSnCl3+BuSH\u2192Bu2SnS+3HCl<\/span>BuSnCl<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>BuSH<\/span><\/span>\u2192<\/span><\/span>Bu<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>SnS<\/span><\/span>+<\/span><\/span>3<\/span>HCl<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n

\u5de5\u827a\u6b65\u9aa4\uff1a<\/h5>\n
    \n
  1. \u539f\u6599\u51c6\u5907<\/strong>\uff1a\u5c06\u4e01\u57fa\u6c2f\u5316\u9521\u548c\u4e01\u57fa\u786b\u9187\u6309\u4e00\u5b9a\u6bd4\u4f8b\u79f0\u91cf\uff0c\u540c\u65f6\u51c6\u5907\u597d\u5e72\u71e5\u7684\u53cd\u5e94\u5bb9\u5668\u548c\u6eb6\u5242\u3002<\/li>\n
  2. \u53cd\u5e94\u6761\u4ef6\u63a7\u5236<\/strong>\uff1a\u5728\u6c2e\u6c14\u4fdd\u62a4\u4e0b\uff0c\u5c06\u539f\u6599\u6eb6\u89e3\u4e8e\u6eb6\u5242\u4e2d\uff0c\u5982\u4e8c\u6c2f\u7532\u70f7\u6216\u56db\u6c22\u544b\u5583\uff0c\u7136\u540e\u5728\u6e29\u548c\u7684\u52a0\u70ed\u6761\u4ef6\u4e0b\u6405\u62cc\u6df7\u5408\u7269\u3002<\/li>\n
  3. \u526f\u4ea7\u7269\u53bb\u9664<\/strong>\uff1a\u53cd\u5e94\u5b8c\u6210\u540e\uff0c\u901a\u8fc7\u8fc7\u6ee4\u6216\u84b8\u998f\u7684\u65b9\u5f0f\u9664\u53bb\u672a\u53cd\u5e94\u7684\u539f\u6599\u548c\u526f\u4ea7\u7269\uff0c\u5982\u76d0\u9178\u53ef\u4ee5\u901a\u8fc7\u6c34\u6d17\u7b49\u65b9\u5f0f\u9664\u53bb\u3002<\/li>\n
  4. \u4ea7\u54c1\u7eaf\u5316<\/strong>\uff1a\u901a\u8fc7\u67f1\u5c42\u6790\u3001\u7ed3\u6676\u6216\u84b8\u998f\u7b49\u624b\u6bb5\u8fdb\u4e00\u6b65\u63d0\u7eaf\u4ea7\u54c1\u3002<\/li>\n
  5. \u6210\u54c1\u68c0\u9a8c<\/strong>\uff1a\u4ea7\u54c1\u9700\u8fdb\u884c\u8d28\u91cf\u68c0\u6d4b\uff0c\u5305\u62ec\u7eaf\u5ea6\u3001\u989c\u8272\u3001\u6bd4\u91cd\u548c\u6298\u5149\u7387\u7b49\u6307\u6807\u7684\u6d4b\u5b9a\uff0c\u4ee5\u786e\u4fdd\u7b26\u5408\u6807\u51c6\u3002<\/li>\n<\/ol>\n

    \u5408\u6210\u8def\u7ebf\u4e4b\u4e8c\uff1a\u4e01\u57fa\u9521\u9187\u4e0e\u786b\u5316\u6c22\u7684\u53cd\u5e94<\/h4>\n

    \u53e6\u4e00\u79cd\u5408\u6210\u9014\u5f84\u662f\u5229\u7528\u4e01\u57fa\u9521\u9187\uff08Bu2SnOH\uff09\u4e0e\u786b\u5316\u6c22\uff08H2S\uff09\u53cd\u5e94\uff0c\u751f\u6210\u4e01\u57fa\u786b\u9187\u9521\u3002\u53cd\u5e94\u65b9\u7a0b\u5f0f\u5982\u4e0b\uff1a<\/p>\n

    Bu2SnOH+H2S\u2192Bu2SnS+H2O<\/span>Bu<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>SnOH<\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span><\/span>\u2192<\/span><\/span>Bu<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>SnS<\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n

    \u5de5\u827a\u6b65\u9aa4\uff1a<\/h5>\n
      \n
    1. \u539f\u6599\u6df7\u5408<\/strong>\uff1a\u5728\u60f0\u6027\u6c14\u4f53\u73af\u5883\u4e0b\uff0c\u5c06\u4e01\u57fa\u9521\u9187\u4e0e\u786b\u5316\u6c22\u6c14\u4f53\u6df7\u5408\u3002<\/li>\n
    2. \u53cd\u5e94\u50ac\u5316<\/strong>\uff1a\u53ef\u80fd\u9700\u8981\u50ac\u5316\u5242\uff08\u5982\u9178\u6216\u78b1\uff09\u4fc3\u8fdb\u53cd\u5e94\u8fdb\u884c\u3002<\/li>\n
    3. \u4ea7\u7269\u5206\u79bb<\/strong>\uff1a\u901a\u8fc7\u84b8\u998f\u6216\u5176\u4ed6\u7269\u7406\u65b9\u6cd5\u5206\u79bb\u51fa\u4ea7\u7269\u548c\u672a\u53cd\u5e94\u7684\u539f\u6599\u3002<\/li>\n
    4. \u7cbe\u5236<\/strong>\uff1a\u91c7\u7528\u9002\u5f53\u7684\u65b9\u6cd5\u53bb\u9664\u6742\u8d28\uff0c\u63d0\u9ad8\u4ea7\u7269\u7eaf\u5ea6\u3002<\/li>\n<\/ol>\n

      \u5de5\u827a\u6ce8\u610f\u4e8b\u9879\uff1a<\/h4>\n